94423-72-0

Basic information

• Product Name: (perchlorato)(tetramesitylporphyrinato)iron(III)
• CAS NO: 94423-72-0
• Molecular Weight: 936.353
• Mol File: 94423-72-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (perchlorato)(tetramesitylporphyrinato)iron(III)(CAS DataBase Reference)
• NIST Chemistry Reference: (perchlorato)(tetramesitylporphyrinato)iron(III)(94423-72-0)
• EPA Substance Registry System: (perchlorato)(tetramesitylporphyrinato)iron(III)(94423-72-0)

Safety Data

• Hazardous Substances Data: 94423-72-0(Hazardous Substances Data)

Upstream product

• 136096-56-5 5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride 
• 93842-71-8 bis(perchlorato)(5,10,15,20-tetramesitylporphyrinato)iron(IV) 
• 93862-19-2 ((CH₃)3C₆H₂)4C₂₀H₈N₄Fe(OCH₃)2 

Downstream Products

• 93842-71-8 C₅₆H₅₂Cl₂FeN₄O₈ 
• 253669-78-2 Fe(C₅H₂N(C₆H₂(CH₃)3))4(5-CH₃C₃H₃N₂)2(ClO₄) 
• 156877-48-4 C₂₀N₄FeH₈[C₆H₂(CH₃)3]4I 
• 93842-72-9 (methoxytetramesitylporphyrinato)iron(III) 
• 93842-71-8 bis(perchlorato)(5,10,15,20-tetramesitylporphyrinato)iron(IV) 
• 93862-19-2 ((CH₃)3C₆H₂)4C₂₀H₈N₄Fe(OCH₃)2 
• 142565-48-8 perp-Fe(C₅H₂N(C₆H₂(CH₃)3))4(4-NCC₅H₄N)2(ClO₄) 
• 95724-73-5 (perchlorato)(5,10,15,20-tetramesitylporphyrinato)oxoiron(IV) 

Relevant articles and documents

One-electron oxidized product of difluoroiron(iii) porphyrin: Is it iron(iv) porphyrin or iron(iii) porphyrin π-cation radical?

The electronic structure of [Fe(TMP)F2], which is formally a one-electron oxidation equivalent above [FeIII(TMP)F 2]-, has been examined in solution by 1H NMR, UV-Vis, and Moessbauer spectroscopy. In CD2Cl2-CD 3OD solution at 193 K, the pyrrole-H and m-H signals appeared at 128.2 and 116.7 ppm, respectively. The UV-Vis spectrum showed broad absorption bands at 560-680 nm. The Moessbauer spectrum taken in frozen toluene-methanol solution exhibited a very broad single line from which the IS and QS values were determined by computer simulation to be 0.50 and 0.14 mm s-1, respectively. On the basis of these results, it was concluded that the one-electron oxidized product of [Fe(TMP)F2]- should be formulated as the iron(iii) radical cation [FeIII(TMP) F2], not as iron(iv) porphyrin [FeIV(TMP)F2] as previously suggested.

Effect of imidazole and phenolate axial ligands on the electronic structure and reactivity of oxoiron(IV) porphyrin π-cation radical complexes: Drastic increase in oxo-transfer and hydrogen abstraction reactivities

To study the effect of axial ligands on the electronic structure and reactivity of compound I of peroxidases and catalases, oxoiron(IV) porphyrin π-cation radical complexes with imidazole, 2-methylimidazole, 4(5)-methylimidazole, and 3-fluoro-4-nitropheno