944338-76-5

Basic information

• Product Name: 1-benzyl-1,3-dimethyl-3-o-tolylurea
• Synonyms: 1-benzyl-1,3-dimethyl-3-o-tolylurea
• CAS NO: 944338-76-5
• Molecular Weight: 268.359
• Mol File: 944338-76-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-benzyl-1,3-dimethyl-3-o-tolylurea(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzyl-1,3-dimethyl-3-o-tolylurea(944338-76-5)
• EPA Substance Registry System: 1-benzyl-1,3-dimethyl-3-o-tolylurea(944338-76-5)

Safety Data

• Hazardous Substances Data: 944338-76-5(Hazardous Substances Data)

Upstream product

• 13143-13-0 N-benzyl-N’-(2-methylphenyl)urea 
• 74-88-4 methyl iodide 

Downstream Products

• 944338-89-0 (+/-)-1,3-dimethyl-1-(phenyl-o-tolyl-methyl)urea 
• 42882-30-4 (+/-)-N-methyl-1-phenyl-1-o-tolylmethanamine 

Relevant articles and documents

Substituted diarylmethylamines by stereospecific intramolecular electrophilic arylation of lithiated ureas

On lithiation, N-benzyl ureas varying N′-aryl substituents undergo a migration of the aryl ring to the ∞ carbon of the N-benzyl group. With chiral, enantiomerically pure N-∞-methylbenzyl ureas, the rearrangement is stereospecific and creates a new, fully substituted stereogenic center ∞ to N. Removal of the urea function by N-nitrosation and hydrolysis allows the synthesis of chiral tertiary carbinamines in high enantiomeric purity. Copyright