944389-74-6Relevant articles and documents
Stereodivergent synthesis of both (2S)- and (2R)-1-monoricinolein derivatives by lipase-catalyzed hydrolysis or transesterification directed to new ferroelectric liquid crystals
Hachiya, Iwao,Sugiura, Yoshihumi,Araki, Hiromasa,Inaoka, Osamu,Shimizu, Makoto,Akita, Masatsugu,Hamaguchi, Takashi
, p. 915 - 918 (2007)
The preparation of both (2S)- and (2R)-1-monoricinolein derivatives has been developed to synthesize ferroelectric liquid crystals. Lipase-catalyzed hydrolysis of 2-protected-1,3-diricinoleins provided (2S)-1-monoricinolein derivatives with high diastereoselectivities, while transesterification of 2-protected glycerols with vinyl recinoleate gave (2R)-1-monoricinolein counterparts in good yields with high diastereoselectivities.
