944401-59-6Relevant articles and documents
Stereoselective total synthesis of (+)-valienamine and (+)-4-epi- valienamine via a ring-closing enyne metathesis protocol
Radha Krishna, Palakodety,Srinivas Reddy
, p. 209 - 212 (2009)
Stereoselective total synthesis of (+)-valienamine is reported utilizing Sharpless asymmetric dihydroxylation, diastereoselective Carreira alkynylation, and ring-closing enyne metathesis (RCEYM) as key steps from L-serine. A similar strategy is also reported for the first total synthesis of (+)-4-epi- valienamine. Georg Thieme Verlag Stuttgart.