94445-38-2

Basic information

• Product Name: methyl β-benzylindenylindene-β-carboxylate
• CAS NO: 94445-38-2
• Molecular Weight: 276.335
• Mol File: 94445-38-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl β-benzylindenylindene-β-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl β-benzylindenylindene-β-carboxylate(94445-38-2)
• EPA Substance Registry System: methyl β-benzylindenylindene-β-carboxylate(94445-38-2)

Safety Data

• Hazardous Substances Data: 94445-38-2(Hazardous Substances Data)

Upstream product

• 71-43-2 benzene 
• 35847-40-6 1-diazo-(1H)-indene 
• 94445-37-1 methyl (Z)-diazo-1H-inden-1-ylidenepropanoate 

Relevant articles and documents

Dipolar cycloaddition reactions of diazoindene and the thermal behavior of the cycloadducts

A study of the dipolar cycloaddition behavior of diazoindene toward electron-deficient acetylenic and olefinic dipolarophiles has been carried out.Reactions with alkynes afford transient 1,3-dipolar cycloadducts.Product formation can be attributed to a substituent-dependent partioning between spiro 3H-pyrazole adducts and ring opened diazoalkenes.The initially formed cycloadducts lose nitrogen to give a spirocyclopropene derivative or undergo the van Alpen - Huttel rearrangement.When olefinic dipolarophiles are used, nitrogen deficient 1:1 adducts are isolated.The formation of the product involves the further loss of nitrogen from the initially formed spiropyrazoline adduct.