944733-23-7

Upstream product

• 4132-26-7 2,3,4,6-tetra-O-benzyl 1,5-anhydro-D-arabino-hex-1-enitol 
• 667-27-6 Ethyl bromodifluoroacetate 
• 944733-22-6 ethyl 2,2-difluoro-2-(3,4,6-tri-O-benzyl-α-D-arabino-hexopyranosid-2-ulosyl)acetate 

Relevant academic research and scientific papers

Addition of electrophilic radicals to 2-benzyloxyglycals: Synthesis and functionalization of fluorinated α-C-glycosides and derivatives

A new method for the synthesis of fluorinated α-C-glycosides is described. The reactions between highly electrophilic radicals (fluorinated or unfluorinated) and a 2-benzyloxyglucal or galactal provide 2-keto-D-arabino- or 2-keto-D-lyxo-hexopyranosides th

Addition of difluoromethyl radicals to glycals: A new route to α-CF2-D-glycosides

The synthesis of synthetically useful α-CF2 glycosides by radical addition of ethyl bromodifluoroacetate onto 2-benzyloxyglycals Is described. The methodology provides an access to α-O-glycoside mimics and, potentially, to valuable α-O-glycocon