94516-97-9Relevant academic research and scientific papers
An Efficient Synthesis of Functionalized Tricyclo1.6>dodec-4-enes by a Stereoselective Intramolecular Diels-Alder Reaction
Shishido, Kozo,Hiroya, Kou,Ueno, Yutaka,Fukumoto, Keiichiro,Kametani, Tetsuji,Honda, Toshio
, p. 829 - 836 (2007/10/02)
An efficient and highly stereoselective synthesis of functionalized tricyclo1.6>dodec-4-enes (1c,e,f-h), which would be useful and common synthons for constructing basic carbon frameworks of various kinds of natural products, is described.The key feature of the synthesis was a stereoselective intramolecular Diels-Alder reaction of the cyclohexanone derivatives (10c,e,f-h), which were easly derived from cyclohexanone in 4-5 steps.The whole structure and the stereochemistry of a major cycloadduct (1e) was established by a single-crystal X-ray analysis.
A STEREOSELECTIVE SYNTHESIS OF A FUNCTIONALIZED TRICYCLO3,8.>DODEC-4-ENE BY AN INTRAMOLECULAR DIELS-ALDER REACTION
Shishido, Kozo,Hiroya, Kou,Ueno, Yutaka,Fukumoto, Keiichiro,Kametani, Tetsuji,Honda, Toshio
, p. 1653 - 1656 (2007/10/02)
An intramolecular Diels-Alder reaction of the cyclohexatrienone derivatives gives the title compounds, which have a useful structural feature for constructing basic carbon frameworks of some kinds of natural products, in a stereoselective manner.
