94563-21-0Relevant academic research and scientific papers
A Sn atom-economical approach toward arylstannanes: Ni-catalysed stannylation of aryl halides using Bu3SnOMe
Komeyama, Kimihiro,Asakura, Ryota,Takaki, Ken
supporting information, p. 8713 - 8716 (2015/08/24)
Stannylation of carbon-halogen bonds is one of the most promising and straightforward approaches for the preparation of organostannane compounds. Although a wide variety of methods are now available, all protocols require the use of highly nucleophilic organometals or wasteful stannyl sources like distannanes. Here, we report a new nickel-catalysed stannylation of aryl and alkenyl-halides using Bu3SnOMe as a stannyl source to afford aryl and vinyl-stannanes, respectively. This method enables the stannylation of not only bromides, but also chlorides and triflates to furnish functionalized aryl- and alkenyl-stannanes without the release of wasteful and toxic stannyl byproducts.
New Functional Vinyltin Compounds via Diels-Alder Reactions
Jousseaume, Bernard
, p. 1452 - 1453 (2007/10/02)
New vinyltin reagents are obtained via Diels-Alder reactions, from acetylenic tin derivatives bearing an ester or nitrile group.
