945656-11-1Relevant academic research and scientific papers
Preliminary investigation of the [3+2] cycloaddition reactions of 2-alkylidenephosphiranes
Tran Huy, Ngoc Hoa,Ricard, Louis,Mathey, Francois
, p. 3614 - 3616 (2007)
The 2-alkylidenephosphirane complex 1 reacts with norbornene and dimethyl acetylenedicarboxylate at 100°C in toluene to give the corresponding [3+2] cycloadducts. With norbornene, only the P-C distal bond is involved, whereas with acetylenedicarboxylate,
