945657-30-7Relevant academic research and scientific papers
Facile synthesis of 4-functionalized cyclopentenones
Ghorai, Sujit Kumar,Hazra, Nirmal Kumar,Mal, Dipakranjan
, p. 1949 - 1956 (2007)
1-8-Diazabicyclo[5.4.0]undec-7-ene(DBU)-catalyzed Michael addition of nitroalkanes to dicyclopentadienone (1) followed by flash vacuum pyrolysis (FVP) provided a high-yielding synthesis of extremely pure 4-nitroalkyl cyclopentenones (3). The optimized Nef reaction of the nitro adducts (2) provided 4-ketoalkyl cyclopentenones (5) in the similar way. Copyright Taylor & Francis Group, LLC.
