94568-76-0

Basic information

• Product Name: 1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-amine
• Synonyms: 1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-amine;1,1,3-Trimethyl-indan-4-ylamine
• CAS NO: 94568-76-0
• Molecular Formula: C12H17N
• Molecular Weight: 175.27008
• Mol File: 94568-76-0.mol

Chemical Properties

• Boiling Point: 264.4℃ at 101.33kPa
• Appearance: /
• Density: 0.98 at 20℃
• Vapor Pressure: 0.2-0.39Pa at 20-25℃
• CAS DataBase Reference: 1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-amine(94568-76-0)
• EPA Substance Registry System: 1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-amine(94568-76-0)

Safety Data

• Hazardous Substances Data: 94568-76-0(Hazardous Substances Data)

Usage

Uses

4-Amino-1,1,3-trimethylindane is used as a reagent in the synthesis of (difluoromethylnicotinic)indanyl carboxamides as fungicides useful in crop protection.

Upstream product

• 125349-37-3 (3R)-1,1,3-trimethyl-4-aminoindane 
• 746625-44-5 2-(1,3-dimethylbut-2-enyl)aniline 
• 4325-82-0 4-methyl pent-3-en-2-ol 
• 62-53-3 aniline 
• 147-47-7 2,2,4-trimethyl-1,2-dihydroquinoline 
• 5855-23-2 1-(2,2,4-trimethylquinolin-1(2H)-yl)ethan-1-one 
• 4497-59-0 1-acetyl-2,2,4-trimethyl-1,2,3,4-tetrahydroquinoline 
• 4497-58-9 1,2,3,4-tetrahydro-2,2,4-trimethylquinoline 

Downstream Products

• 1246263-35-3 2-fluoro-6-(trifluoromethyl)-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)benzamide 
• 1616291-21-4 4-amino-1,1,3-trimethylindane hydrochloride 

Relevant articles and documents

PROCESS FOR PRODUCING SUBSTITUTED 4-AMINOINDANES

The present invention primarily relates to a process for producing certain substituted 2-allylanilines of the hereinbelow-defined formula (I) and their use in a process for producing substituted 4-aminoindane derivatives of the hereinbelow-defined formula

METHOD FOR PREPARING SUBSTITUTED 4-AMINOINDANE DERIVATIVES

The present invention relates to a method for preparing substituted 4-aminoindane derivatives of the general formula (I) by rearrangement of compounds of the formula (II) in HF, wherein R1, R2, R3, R4, and R5 have the definitions as specified in the description.

METHOD FOR PRODUCING RACEMATE OF COMPOUND

A method for producing a racemate of a compound represented by Formula (1), including bringing a transition metal catalyst into contact with an optically active form of the compound represented by Formula (1): [in Formula (1), a ring X1 represents an aromatic ring; R1 represents a C1-6 alkyl group, a C3-8 cycloalkyl group, or a C1-6 halo-alkyl group; R2 is a group different from R1 and represents a C1-6 alkyl group, a C3-8 cycloalkyl group, or a C1-6 halo-alkyl group, or R2 and the ring X1 are bonded to each other to form a ring; a hydrogen atom(s) of the ring X1 is optionally replaced with a C1-6 alkyl group, a C1-6 halo-alkyl group, a cyano group, a nitro group, a C1-6 alkoxy group, or a halogen atom; and * represents an asymmetric carbon atom].

METHOD FOR PRODUCING PURIFIED FORM OF AMINE COMPOUND

A method for producing a purified amine compound represented by the formula (1), including: step (A) of reacting a crude form of the amine compound represented by the formula (1) with a hydrogen halide in the presence of water and an organic solvent insoluble in water; step (B) of separating a phase in which a hydrogen halide salt of the amine compound represented by the formula (1) produced in step (A) is dissolved from the other phase (es) ; step (C) of precipitating the hydrogen halide salt of the amine compound represented by the formula (1) from the phase obtained in step (B) in which the hydrogen halide salt of the amine compound represented by the formula (1) is dissolved; and step (D) of isolating the hydrogen halide salt of the amine compound represented by the formula (1) precipitated in step (C), and reacting the salt with a base.

BENZAMIDIC COMPOUNDS HAVING FUNGICIDAL ACTIVITY AND RELATIVE USE

The present invention relates to benzamidic compounds having general formula (I): wherein: Rx represents a halogen atom or a methyl group possibly substituted by fluorine atoms; R1, R2, R3, independently from each other, represent a C1- C3 alkyl group; R4 represents a hydrogen atom or a C1-C3 alkyl group; Ry represents a halogen atom, a C1-C4 alkyl group, a C1-C4 haloalkyl group, a C1-C4 alcoxy group, a C1-C4 haloalcoxy group; n represents an integer ranging of from 0 to 3. The present invention also relates to the use of the above benzamidic compounds for the control of fungi, bacteria and phytopathogenic viruses of agricultural crops.

Processes for the preparation of pesticides and intermediates

There is disclosed a process for the preparation of an indanylamine compound of general formula STR1 wherein R1 represents an optionally substituted alkyl group, and R2, R3 and R4 independently represent a hydrogen atom or an optionally substituted alkyl group, the process including the steps of hydrogenating a compound of general formula STR2 wherein R1, R2, R3 and R4 are as described above and R5 and R6 independently represent a halogen atom, a hydroxyl, nitro or cyano group, or an optionally substituted alkyl, alkoxy, alkoxycarbonyl, alkylcarboxy or alkylamino group provided that R5 and R6 represent different atoms or groups, and subsequent rearrangement and derivatization of the product thereof. Compounds of general formula I may be used to prepare preferred stereoisomers of fungicidal N-indanyl carboxamide compounds.