945740-83-0Relevant academic research and scientific papers
Intramolecular carbolithiation of 2,6-dilithio-1,6-heptadienes: An experimental and theoretical study
Sanz, Roberto,Ignacio, Jose M.,Rodriguez, Miguel A.,Fananas, Francisco J.,Barluenga, Jose
, p. 4998 - 5008 (2008/02/04)
2,6-Dilithio-1,6-heptadienes 3 undergo intramolecular carbolithiation in Et2O/N,N,N′,N′-tetramethylethylenediamine (TMEDA) at the lithiated double bonds to afford 1,2-bis(lithiomethyl)cyclopentenes 5. Reaction of these dianions with electrophil
