945865-99-6Relevant academic research and scientific papers
Group 2 Catalysis for the Atom-Efficient Synthesis of Imidazolidine and Thiazolidine Derivatives
Arrowsmith, Merle,Hill, Michael S.,Kociok-K?hn, Gabriele
, p. 10548 - 10557 (2015)
A wide variety of functionalised imidazolidine-2-ones and -thiones, 2-imino-imidazolidines and thiazolidine-2-thiones have been synthesised under very mild reaction conditions by using simple and cost-effective alkaline earth bis(amide) precatalysts, [Ae{
Method for catalyzing addition reaction of alkyne and carbodiimide
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Paragraph 0051; 0052; 0053; 0054, (2019/09/13)
The invention relates to a method for catalyzing an addition reaction of one alkyne and one carbodiimide. The method comprises the following step: performing a reaction on one alkyne represented by aformula (1) shown in the description and an N,N'-diisopr
CNC-pincer rare-earth metal amido complexes with a diarylamido linked biscarbene ligand: synthesis, characterization, and catalytic activity
Gu, Xiaoxia,Zhu, Xiancui,Wei, Yun,Wang, Shaowu,Zhou, Shuangliu,Zhang, Guangchao,Mu, Xiaolong
, p. 2372 - 2379 (2014/06/09)
In preparation of CNC-pincer rare-earth metal amido complexes with a diarylamido linked biscarbene ligand, it is found that conditions have a key influence on final products. Reaction of a THF suspension of bis[2-(3-benzylimidazolium)-4-methylphenyl]amine
Cyclopentadienyl-free rare-earth metal amides [{(CH2SiMe 2){(2,6iPr2C6H3)N} 2}Ln{N(SiMe3)2}(THF)] as highly efficient versatile catalysts for C-C and C-N bond formation
Wu, Yunjun,Wang, Shaowu,Zhang, Lijun,Yang, Gaosheng,Zhu, Xiancui,Zhou, Zhihong,Zhu, Hong,Wu, Shihong
supporting information; experimental part, p. 326 - 332 (2010/04/06)
Efficient methods have been developed for the direct synthesis of amides from aldehydes and a straightforward route to propiolamidines using cyclopentadienyl-free rare-earth metal amides [{(CH2SiMe 2){(2,6-iPr2C6H3)N} 2}Ln{N(SiMe3)2}(THF)] [Ln = Yb (1), Y (2), Dy (3), Sm (4), Nd (5)] as versatile catalysts, The results indicate that in the direct synthesis of amides from aldehydes the catalysts have the activity order 2>1～3～4～5. These methods have the advantage of easy preparation of the catalysts, low catalyst loading, high conversion of substrates to products, mild reaction conditions, and compatibility with a wide range of substrates.
