945903-61-7

Upstream product

• 99438-31-0 erythro-(-)-3-methyl-4-penten-2-ol 
• 1197349-28-2 C₂₄H₃₄O₃Si 
• 1322574-47-9 (S,E)-4-((tert-butyldiphenylsilyl)oxy)-3-methylpent-2-enal 
• 1322574-63-9 C₂₂H₃₀O₂Si 
• 1197349-14-6 C₂₄H₃₂O₃Si 
• 945903-60-6 (3S,4S)-4-tert-butyldiphenylsilyloxy-3-methyl-pentan-1-ol 
• 945903-59-3 (3S,4S)-4-tert-butyldiphenylsilyloxy-3-methyl-pent-1-ene 
• 1204685-99-3 methyl (3S,4S)-4-(tert-butyldiphenylsilyloxy)-3-methylpentanoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 945903-62-8 (1E,4S,5S)-5-tert-butyldiphenylsilyloxy-1-iodo-4-methyl-hex-1-ene 
• 945903-63-9 (1E,3E,6S,7S)-7-tert-butyldiphenylsilyloxy-6-methyl-1-phenylocta-1,3-diene 
• 946009-48-9 (2S,3S)-dihydrolignarenol B 
• 1197349-20-4 (3S,4R,6S,7S)-7-((tert-butyldiphenylsilyl)oxy)-3,6-dimethyloct-1-en-4-ol 
• 1204686-00-9 (2S,4R,5R,7S,8S)-8-(tert-butyldiphenylsilyloxy)-5-hydroxy-4,7-dimethyl-3-oxononan-2-yl benzoate 
• 1322574-66-2 C₃₅H₄₈N₄O₃SSi 
• 1322574-49-1 C₃₅H₄₈N₄O₅SSi 
• 1322574-65-1 C₂₈H₄₂O₃Si 
• 1322574-48-0 (3S,4R,6S,7S)-7-((tert-butyldiphenylsilyl)oxy)-4-(methoxymethoxy)-3,6-di methyloctan-1-ol 

Relevant academic research and scientific papers

Enantioselective total synthesis of the proposed structure of macrolide iriomoteolide-1b

An enantioselective total synthesis of the proposed structure of macrolide iriomoteolide-1b has been achieved by a convergent protocol, which was featured by an enantioselective organocatalytic transfer hydrogenation of enal, a Julia-Kocienski olefination

Synthesis of the macrocyclic core of iriomoteolide-1a

The fully functionalized macrocyclic core of the marine natural product iriomoteolide-1a has been successfully constructed in a convergent and enantioselective manner.

Synthesis of C13-C23 fragment of Iriomoteolide-1a

Highly efficient asymmetric conjugate addition of MeMgBr to α,β-unsaturated esters catalyzed by CuI/To1-BINAP, Paterson aldol, organocatalytic aldol, and cross-metathesis reactions were applied in the synthesis of C13-C23 fragment of Iriomoteolide-la.

Synthetic studies towards iriomoteolide-1a: Construction of the C13-C23 fragment

A stereoselective synthesis of the C13-C23 segment of iriomoteolide-1a was achieved using, as key steps, a highly stereocontrolled crotylation to build the stereocenters at C18 and C19 and a Julia-Kocienski olefination to establish the C15-C16 E-olefin mo

Towards the biosynthesis of the aromatic products of the Mediterranean mollusc Scaphander lignarius: isolation and synthesis of analogues of lignarenones

Secondary metabolites of the Mediterranean mollusc Scaphander lignarius from different collection sites have been investigated, proving the constant presence of a number of minor metabolites correlated to the already known lignarenones. Complete character