946524-59-0

Upstream product

• 946524-53-4 (3R,3aS,6R,7S,7aS)-3,6-dimethyl-7-(3-methyl-but-3-enyl)-7a-vinyl-hexahydro-benzofuran-2-one 
• 166317-79-9 (2S,5R)-5-methyl-2-((R)-1-methyl-2-triisopropylsilanyloxy-ethyl)-cyclohexan-1-one 
• 946524-58-9 C₁₉H₃₆O₂Si 
• 946524-57-8 C₂₈H₅₄O₂Si₂ 
• 946524-49-8 (1S,2S,3R,6S)-3-methyl-6-((R)-1-methyl-2-triisopropylsilanyloxy-ethyl)-2-((E)-3-methylsilanyl-but-2-enyl)-1-vinyl-cyclohexan-1-ol 
• 946524-47-6 (2S,3R,6S)-3-methyl-6-((R)-1-methyl-2-triisopropylsilanyloxy-ethyl)-2-((E)-3-methylsilanyl-but-2-enyl)-cyclohexan-1-one 
• 946524-52-3 (3R,3aS,6R,7S,7aS)-3,6-dimethyl-7-(3-oxo-butyl)-7a-vinyl-hexahydro-benzofuran-2-one 
• 946524-51-2 (3R,3aS,6R,7S,7aS)-3,6-dimethyl-7-((E)-3-methylsilanyl-but-2-enyl)-7a-vinylhexahydro-benzofuran-2-one 

Relevant academic research and scientific papers

Synthesis of (+)-dihydro-epi-deoxyarteannuin

The synthesis of (+)-dihydro-epi-deoxyarteannuin B (3) from (-)-isopulegol is described. Difficulties in the alkylation of menthone derivatives (e.g., 4a → 6a) were overcome by using Noyori's zincate enolate method. Related problems with nucleophilic addi