946612-08-4Relevant academic research and scientific papers
An expeditious, highly efficient, catalyst-free and solvent-free synthesis of nitroamines and nitrosulfides by Michael addition
Choudhary, Garima,Peddinti, Rama Krishna
body text, p. 276 - 282 (2011/04/17)
A simple, atom economical, fast and highly efficient green protocol has been developed for the synthesis of nitroamines and nitrosulfides by the Michael addition of amines and thiols to nitroolefins by simple mixing or grinding. This catalyst-free and solvent-free green approach provided the addition products in quantitative yield within minutes at room temperature. This procedure does not require any water quenches, solvent separations and purification steps such as recrystallization and column chromatography.
Synthesis of some 2-aminonitroethanes via silica gel-catalyzed nitro-Mannich reaction
Mahasneh, Ali S.
, p. 1162 - 1165 (2008/09/18)
A direct one pot, three-component nitro-Mannich reaction of a nonenolizable aldehyde, aniline or one of its ring-substituted derivatives and nitromethane was carried out on silica gel surface. The products of the reaction, 2-aminonitroethane, were obtaine
