947138-68-3Relevant academic research and scientific papers
Double HCl elimination and configuration change in the square-planar palladium complex trans-[{(Ph2PC6H4CONH)2C6H4}PdCl2] under Suzuki conditions: Isolation and molecular structure of cis-[{(Ph2PC6H4CON)2C6H4}Pd]
Chahen, Ludovic,Karmazin-Brelot, Lydia,Süss-Fink, Georg
, p. 1151 - 1154 (2006)
The trans-configurated square-planar palladium complex trans-[{(Ph2PC6H4CONH)2C6H4}PdCl2] (1), which catalyzes the Suzuki cross coupling of 4-bromotoluene with phenylboronic acid, was found to react with potassium carbonate in toluene at 90 °C (Suzuki conditions) to give cis-[{(Ph2PC6H4CON)2C6H4}Pd] (2). The single-crystal X-ray structure analysis of 2 reveals the square-planar palladium center to be in a cis configuration. The trans-cis configuration change at palladium is possible because of the elimination of two HCl equivalents in the conversion of 1 into 2. Both complexes 1 and 2 show approximately the same catalytic performance for Suzuki reactions, suggesting 2 to be the catalytically active species.
