947256-95-3

Basic information

• Product Name: phenyl 2,3,4-tri-O-benzyl-6-O-(6-O-benzyl-2,3,4-tri-O-tert-butyldimethylsilyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside
• Synonyms: phenyl 2,3,4-tri-O-benzyl-6-O-(6-O-benzyl-2,3,4-tri-O-tert-butyldimethylsilyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside
• CAS NO: 947256-95-3
• Molecular Weight: 1137.75
• Mol File: 947256-95-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl 2,3,4-tri-O-benzyl-6-O-(6-O-benzyl-2,3,4-tri-O-tert-butyldimethylsilyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2,3,4-tri-O-benzyl-6-O-(6-O-benzyl-2,3,4-tri-O-tert-butyldimethylsilyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside(947256-95-3)
• EPA Substance Registry System: phenyl 2,3,4-tri-O-benzyl-6-O-(6-O-benzyl-2,3,4-tri-O-tert-butyldimethylsilyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside(947256-95-3)

Safety Data

• Hazardous Substances Data: 947256-95-3(Hazardous Substances Data)

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 2936-70-1 (2R,3S,4S,5R,6S)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4,5-triol 
• 87470-73-3 phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 947256-84-0 phenyl 6-O-benzyl-2,3,4-tri-O-tert-butyldimethylsilyl-1-thio-α-D-glucopyranoside 
• 947256-83-9 phenyl 6-O-benzyl-2,3,4-tri-O-tert-butyldimethylsilyl-1-thio-β-D-glucopyranoside 

Relevant articles and documents

"Super armed" glycosyl donors: Conformational arming of thioglycosides by silylation

Glycosyl donors protected with bulky silyl protective groups (tert-butyldimethylsilyl, TBS), on the 2-, 3-, and 4-OH groups were found to have superior reactivity compared with benzylated thioglucosides. The enhanced reactivity is explained by the stereoe