947257-10-5

Basic information

• Product Name: phenyl 2,3,4-tri-O-benzyl-6-O-(6-deoxy-2,3,4-tri-O-tert-butyldimethylsilyl-α-L-mannopyranosyl)-1-thio-β-D-glucopyranoside
• Synonyms: phenyl 2,3,4-tri-O-benzyl-6-O-(6-deoxy-2,3,4-tri-O-tert-butyldimethylsilyl-α-L-mannopyranosyl)-1-thio-β-D-glucopyranoside
• CAS NO: 947257-10-5
• Molecular Weight: 1031.63
• Mol File: 947257-10-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl 2,3,4-tri-O-benzyl-6-O-(6-deoxy-2,3,4-tri-O-tert-butyldimethylsilyl-α-L-mannopyranosyl)-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2,3,4-tri-O-benzyl-6-O-(6-deoxy-2,3,4-tri-O-tert-butyldimethylsilyl-α-L-mannopyranosyl)-1-thio-β-D-glucopyranoside(947257-10-5)
• EPA Substance Registry System: phenyl 2,3,4-tri-O-benzyl-6-O-(6-deoxy-2,3,4-tri-O-tert-butyldimethylsilyl-α-L-mannopyranosyl)-1-thio-β-D-glucopyranoside(947257-10-5)

Safety Data

• Hazardous Substances Data: 947257-10-5(Hazardous Substances Data)

Upstream product

• 1214-98-8 phenyl 1-thio-α-L-rhamnopyranose 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 947256-89-5 phenyl 6-deoxy-2,3,4-tri-O-tert-butyldimethylsilyl-1-thio-α-L-mannopyranoside 
• 87470-73-3 phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside 

Relevant articles and documents

"Super armed" glycosyl donors: Conformational arming of thioglycosides by silylation

Glycosyl donors protected with bulky silyl protective groups (tert-butyldimethylsilyl, TBS), on the 2-, 3-, and 4-OH groups were found to have superior reactivity compared with benzylated thioglucosides. The enhanced reactivity is explained by the stereoe