94726-46-2Relevant academic research and scientific papers
1,4-Fragmentation of γ-Tributylstannyl Alcohols by a Hypervalent Organoiodine Compound: a New Synthesis of Unsaturated Carbonyl Compounds
Ochiai, Masahito,Ukita, Tatsuzo,Nagao, Yoshimitsu,Fujita, Eiichi
, p. 1007 - 1008 (2007/10/02)
1,4-Fragmentation of γ-tributylstannyl alcohols using iodosylbenzene, boron trifluoride-diethyl ether, and dicyclohexylcarbodiimide produces unsaturated carbonyl compounds; the fragmentation, combined with conjugate addition of tributylstannyl-lithium and reduction or alkylation, offers an efficient procedure for the reductive and alkylative ring opening of cyclic vinyl ketones.
