947342-47-4Relevant articles and documents
Inexpensive synthesis of 1,4-bis(4-aminophenoxy)-2- (6-oxido-6H-dibenz oxaphosphorin-6-yl) phenylene and its oxygen-plasma resistant polyamides
Lin, Ching Hsuan,Chang, Sheng Lung,Fang, Yu Ting,Hwang, Hann Jang,Tsai, Cheng Hsien
experimental part, p. 414 - 421 (2011/02/23)
Inexpensive synthesis of diamine, 1,4-bis(4-nitrophenoxy)-2-(6-oxido-6H-dibenz oxaphosphorin-6-yl) phenylene was revealed in this work. Based on the diamine, a series of organosoluble polyamides were prepared by direct polycondensation of the diamine with various aromatic diacids using triphenyl phosphite and pyridine as condensing agents. The number-average molecular weights of the resulting polyamides range from 4.2?×?104 to 10.5?×?104?g/mol, and the weight-average molecular weights are in the range of 7.5-28.2?×?104?g/mol. The Tgs of these polyamides range from 210 to 255?°C by dynamic mechanical analysis. The resulting polyamides are tough and flexible with tensile strength, elongation at break and moduli range from 84 to 101?MPa, 4.8-7.0%, and 2.36-3.22?GPa, respectively. The degradation temperatures (Td 5%) and char yields at 800?°C in nitrogen range from 460 to 486?°C and 59-68?wt%, respectively. The cutoff wavelength of these polyamides falls in the range of 345-366?nm, showing a very light color characteristic. In addition, these polyamides display good oxygen plasma resistance.