947510-24-9Relevant articles and documents
Synthesis, anticancer activity and apoptosis induction of gold(I) complexes containing tris(o-methoxyphenyl)phosphane
Abogosh, Ahmed K.,Ahmad, Saeed,Alanazi, W. A.,Alasmael, Noura,Alghanem, Meshal,Alhoshani, Ali,Isab, Anvarhusein A.,Mahmoud, Mohamed A.,Monim-ul-Mehboob, Muhammad,Peedikakkal, Abdul Malik Puthan,Sulaiman, Adam A. A.
, (2021/09/07)
Four new phosphanegold(I) complexes; [Au{(o-MeO-Ph)3P}Cl] (1), [Au{(o-MeO-Ph)3P}{(Me-Et-Ph)P}]Cl (2), [Au{(o-MeO-Ph)3P}(Ph3P)]Cl (3) and [Au{(o-MeO-Ph)3P}2]Cl (4) (where o-MeO-Ph)3/su
Structural studies of two-coordinate complexes of tris(2-methoxylphenyl)phosphine and tris(4-methoxyphenyl)phosphine with gold(I) halides
Bott, Raymond C.,Healy, Peter C.,Smith, Graham
, p. 2803 - 2809 (2008/10/09)
A series of five gold(I) halide complexes with the two isomeric methoxy-substituted triarylphosphines, tris(2-methoxyphenyl)phosphine [P(oanis)3], [AuP(oanis)3X] [for X = Cl, (1); X = Br, (2) and X = I, (3)] and tris(4-methoxyphenyl)phosphine [P(panis)3], [AuP(panis)3X] [for X = Br (4) and X = I (5)] have been synthesized and characterized by single crystal X-ray diffraction and solution 31P{1H} NMR spectroscopy. The structure determinations confirm the expected presence of linear two-coordination about the gold centres in all five complexes with bond distance and angle data typical of this type of compound [Au-P, 2.239(2)-2.259(3) ?; Au-Cl, 2.294(2) ?; Au-Br, 2.385(2)-2.402(2) ?; Au-I, 2.546(1)-2.554(1) ?; P-Au-X; 175.3(1)-180°]. All analogues except the iodo complex 5 crystallize with one complex molecule in the crystallographic asymmetric unit. The bromo and iodo complexes 2 and 3 constitute a trigonal isomorphous set while the bromo complex 4 is also isomorphous with the previously determined chloro complex [AuP(panis)3Cl]. The 2-methoxy analogues are stabilized by significant methoxy-O?Au interactions.
