947587-76-0

Basic information

• Product Name: (E)-7,11-dimethyl-6,10-dodecadien-2-yne
• Synonyms: (E)-7,11-dimethyl-6,10-dodecadien-2-yne
• CAS NO: 947587-76-0
• Molecular Weight: 190.329
• Mol File: 947587-76-0.mol

Chemical Properties

• CAS DataBase Reference: (E)-7,11-dimethyl-6,10-dodecadien-2-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-7,11-dimethyl-6,10-dodecadien-2-yne(947587-76-0)
• EPA Substance Registry System: (E)-7,11-dimethyl-6,10-dodecadien-2-yne(947587-76-0)

Safety Data

• Hazardous Substances Data: 947587-76-0(Hazardous Substances Data)

Upstream product

• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 

Downstream Products

• 1379679-84-1 (3aS,7aS)-4,4,7a-trimethyloctahydro-1H-inden-1-one trisyl hydrazone 
• 947688-23-5 C₂₆H₃₉ClO₂ 

Relevant articles and documents

Total Synthesis of (-)-Chromodorolide B by a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade

The first total synthesis of a chromodorolide marine diterpenoid is described. The core of the diterpenoid is constructed by a bimolecular radical addition/cyclization/fragmentation cascade that unites two complex fragments and forms two C-C bonds and four contiguous stereogenic centers of (-)-chromodorolide B in a single step. This coupling step is initiated by visible-light photocatalytic fragmentation of a redox-active ester, which can be accomplished in the presence of an iridium or a less-precious electron-rich dicyanobenzene photocatalyst, and employs equimolar amounts of the two addends. Computational studies guided the development of this central step of the synthesis and provide insight into the origin of the observed stereoselectivity.