947601-94-7

Basic information

• Product Name: 1-Ethyl-3-methylimidazolium bicarbonate
• Synonyms: 1-Ethyl-3-methylimidazolium hydrogencarbonate solution ;1-Ethyl-3-methylimidazolium bicarbonate;1-Ethyl-3-methylimidazolium hydrogen carbonate
• CAS NO: 947601-94-7
• Molecular Formula: CHO₃*C₆H₁₁N₂
• Molecular Weight: 0
• Mol File: 947601-94-7.mol
• Article Data: 6

Chemical Properties

• Flash Point: 57 °C
• Appearance: /
• CAS DataBase Reference: 1-Ethyl-3-methylimidazolium bicarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Ethyl-3-methylimidazolium bicarbonate(947601-94-7)
• EPA Substance Registry System: 1-Ethyl-3-methylimidazolium bicarbonate(947601-94-7)

Safety Data

• Hazard Codes: Xn,T,Xi
• Statements: 20/21/22-36/37/38-68/20/21/22-39/23/24/25
• Safety Statements: 26-36/37
• RIDADR: UN 1987 3/PG 3
• Hazardous Substances Data: 947601-94-7(Hazardous Substances Data)

Usage

Type of compound

Ionic liquid

Cation structure

1-Ethyl-3-methylimidazolium (contains an ethyl and methyl substituent on the imidazolium ring)

Anion structure

Bicarbonate (HCO3-)

Low viscosity

Facilitates easy handling and processing

High thermal stability

Resistant to decomposition at high temperatures, suitable for various chemical processes

Solubility in water

Readily dissolves in water, allowing for its use in aqueous systems

Application in CO2 capture

Ability to absorb and store carbon dioxide, reducing greenhouse gas emissions

Use in catalysis

Enhances the rate of chemical reactions, improving efficiency and productivity

Role in electrochemistry

Functions as an electrolyte in energy storage devices, such as batteries and supercapacitors

Potential as a green solvent

Environmentally friendly alternative to traditional solvents, reducing waste and pollution

Use as an electrolyte in energy storage devices

Improves performance and efficiency of energy storage systems

InChI:InChI=1/C6H11N2.CH2O3/c1-3-8-5-4-7(2)6-8;2-1-4-3/h4-6H,3H2,1-2H3;1,3H/q+1;/p-1

Upstream product

• 298-14-6 potassium hydrogencarbonate 
• 65039-08-9 3-ethyl-1-methyl-1H-imidazol-3-ium bromide 
• 65039-09-0 1-ethyl-3-methyl-1H-imidazol-3-ium chloride 
• 584-08-7 potassium carbonate 
• 1355498-33-7 [C₂mim][H(OAc)2][C₂mim(+)-COO(-)] 
• 1017847-51-6 1-ethyl-3-methylimidazolium-2-carboxylate 

Relevant articles and documents

Demonstration of chemisorption of carbon dioxide in 1,3-dialkylimidazolium acetate ionic liquids

Real chemistry: Spectroscopic and crystallographic analyses confirm the chemical reaction of CO2 with carbene present in 1,3- dialkylimidazolium acetate ionic liquids and the supporting role of the acetate ion. When CO2 was bubbled through [C2mim][OAc], formation of the corresponding imidazolium carboxylate, [C2mim +-COO-], could be observed. Copyright

Ascorbic acid based ionic liquids: Recyclable and efficient catalytic systems for the huisgen cycloaddition

A new method for the Huisgen cycloaddition using an ascorbic acid based ionic liquid and a copper catalyst in an ionic liquid, under microwave irradiation, is described. The reaction times are short and a simple procedure for separation of the products is

Ionic liquids as benign catalysts for the carbonylation of amines to formamides

1-Butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO3]), prepared from the reaction of [BMIm]Cl with K2CO3 in methanol, exhibits high activity for the carbonylation of amines to produce formamides. Computational calculation results on the carbonylation reaction of methylamine implies that such high activity of [BMIm][HCO3] could be ascribed to the bi-functional actions of [HCO3]- as a hydrogen atom acceptor and a donor.