947769-20-2

Upstream product

• 947769-23-5 C₂₂H₄₃SiOBr 
• 947769-13-3 C₆H₁₀O₂C₇H₇CO₂C₂H₅NHC₂H₄S 
• 129848-97-1 (E)-6-(benzyloxy)-2-hexen-1-al 
• 947769-19-9 C₆H₁₀O₂C₇H₇CO₂C₂H₅NH 
• 947769-18-8 C₆H₁₀O₂C₇H₇CO₂C₂H₅ 
• 947769-17-7 C₆H₁₀O₂C₇H₆SiC₃H₉CN 
• 947769-16-6 C₂₂H₄₄SiO₂ 
• 947769-15-5 C₂₃H₄₄SiO₃ 

Downstream Products

• 947769-26-8 C₃₈H₆₄SSiO₄H₂ 
• 947769-21-3 C₃₈H₆₄SSiO₄SO₂CH₄ 
• 947769-27-9 C₃₇H₆₄SSiO₆ 
• 947769-28-0 C₃₆H₆₂SiO₄ 

Relevant academic research and scientific papers

Synthesis of the C3-C18 fragment of amphidinolides G and H

A synthesis of an amphidinolides G and H C3-C18 subunits is reported. The C10-C18 segment 4 was prepared by a Negishi cross-coupling, whereas the synthesis of the C3-C9 fragment 5 employed an asymmetric cyanosilylation as the key step. The two segments were coupled by lithiation of iodide 4 and trapping of the anion with amide 5. The allylic epoxide moiety could be synthesized from the protected anti- mesylate 22.