94802-89-8Relevant academic research and scientific papers
Domino Michael-seleno Pummerer type reaction (additive seleno Pummerer reaction)
Hagiwara, Hisahiro,Kafuku, Koji,Sakai, Hitoshi,Kirita, Miki,Hoshi, Takashi,Suzuki, Toshio,Ando, Masayoshi
, p. 2577 - 2578 (2000)
Domino Michael-seleno Pummerer type reaction (additive seleno Pummerer type rearrangement) has been realised by the reaction of 1,3-dicarbonyl compounds with vinyl selenoxides in the presence of amine and chlorosilane. The Royal Society of Chemistry 2000.
Ruthenium catalyzed selective regio-and-mono-allylation of cyclic 1,3-diketones using allyl alcohols as substrates
Gruber, Stefan,Pregosin, Paul S.
experimental part, p. 3235 - 3242 (2010/04/28)
The new ruthenium-sulfonate catalyst Ru(Cp*) (η3-C3H5)(p-CH3C 6H4SO3)2, (Cp*= pentamethylcyclopentadienyl), rapidly and regioselectively mono-all
Sarcosine based indandione hGlyT1 inhibitors
Thomson, Christopher G.,Duncan, Karen,Fletcher, Stephen R.,Huscroft, Ian T.,Pillai, Gopalan,Raubo, Piotr,Smith, Alison J.,Stead, Darren
, p. 1388 - 1391 (2007/10/03)
A series of sarcosine based indandione hGlyT1 inhibitors has been developed. Optimization of substitution around the indandione and sarcosine moieties has led to highly potent inhibitors at hGlyT1, which show selectivity over a number of other receptors.
An Unusual Synthesis of a Dihydrobenzanthrone
Veith, Reiner,Henke, Henning,Aldag, Reinhard,Braun, Manfred
, p. 265 - 268 (2007/10/02)
The reaction of the aldehyde 1 with aluminium trichloride in benzene affords the dihydrobenzanthrone 2.The structure is confirmed by an X-ray analysis.Dehydrogenation of 2 yields the benzanthrone 3, which shows a greenish yellow fluorescence.According to the 1H-NMR and mass spectra, the deuterated products 5 and 6 are formed, when the key reaction is carried out in benzene.
SYNTHESIS OF SPIROCYCLIC DIKETONES RELATED TO FREDERICAMYCIN A
Braun, Manfred,Veith, Reiner
, p. 179 - 182 (2007/10/02)
An intramolecular Friedel-Crafts type reaction of the thioacetals 7a and 7b is the key step in a simple synthesis of the diketones 2a and 2b.
