94835-41-3

Upstream product

• 110-91-8 morpholine 
• 61380-86-7 6-(4-methoxyphenyl)-3-cyano-4-methylsulfanyl-2H-pyran-2-one 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 110-89-4 piperidine 

Relevant academic research and scientific papers

Ultrasound-assisted synthesis, photophysical behaviour and single crystal X-ray analysis of highly functionalized prenylarenes

A rapid, ultrasound assisted base-catalysed metal free synthesis of a novel series linear prenylarenes 17 incorporated with donor-acceptor functionalities is described via carbanion-induced ring transformation of 4-amino-6-aryl-3-cyano-2H-pyran-2-ones 15 with 6-methylhept-5-en-2-one 16 at room temperature with high yields. Notably, all of the synthesised prenylarenes exhibited blue fluorescence in the 406–468 nm region. The stokes shift, optical band gap, and quantum yield of compounds 17a-17l were computed using their absorption and emission spectra. A significant positive solvatochromic effect was observed, and concentration studies revealed the non-aggregating behaviour of synthesised prenylarenes. Single crystal X-ray diffraction analysis of 17d revealed that crystal belongs to triclinic system with P-1 space group with twisted phenyl rings.

Base-promoted regioselective synthesis of 1,2,3,4-terahydroquinolines and quinolines from N-boc-3-piperidone

An efficient synthesis of 1,2,3,4-tetrahydroquinolines with donor and acceptor group has been delineated by base mediated ring transformation of 6-aryl-4-substituted-2H-pyran-2-one-3-carbonitriles by N-boc-3-piperidone followed by consecutive deprotection

Chemoselective synthesis of m-teraryls through ring transformation of 2 H-pyran-2-ones by 2-(1-arylethylidene)-malononitriles

We have developed a simple, efficient and chemoselective approach for the synthesis of m-teraryls by the reaction of 6-aryl-2-oxo-4-(sec.amino)-2H-pyran-3-carbonitriles and 2-(1-arylethylidene)malononitriles under basic conditions. We used 6-aryl-2-oxo-4-

Synthesis, photophysical and anticancer study of D-ring extended estrone analogues

A concise route for the highly substituted ring extended estrone derivatives has been established. This protocol involves very simple, facile and one step ring transformation and cyclization process. The preliminary absorption, emission spectroscopic and

A regioselective synthesis of 2,6-diarylpyridines

A regioselective synthesis of 2,6-diarylpyridines through base (sodium hydroxide in DMSO) catalyzed ring transformation of suitably functionalized 2H-pyran-2-ones with benzamide has been delineated. However, similar reaction of 2H-pyran-2-ones with benzam

Synthesis and fluorescence of 2H-pyrone derivatives for organic light-emitting diodes (OLED)

(Chemical Equation Presented) 2H-Pyrone derivatives were synthesized through the reaction of aryl acetyl compounds with ketene dithioacetals in the presence of sodium hydroxide, and they showed very strong fluorescence in the solid state. The light-emitti

Synthesis and Reactions of 6-Aryl- and 6-Styryl-3-cyano-4-methylthio-2H-pyran-2-ones

The reaction of various types of acetyl compounds with a ketene dithioacetal, methyl 2-cyano-3,3-bis(methylthio)acrylate, in the presence of potassium hydroxide gave the corresponding 6-aryl- and 6-styryl-3-cyano-4-methylthio-2H-pyran-2-one derivatives.Th