94852-99-0

Upstream product

• 94853-06-2 1-((Z)-6-Benzenesulfinyl-3,7-dimethyl-octa-2,7-diene-1-sulfonyl)-4-methyl-benzene 
• 70473-48-2 (Z)-2,6-Dimethyl-3-phenylsulfanyl-8-(toluene-4-sulfonyl)-oct-6-en-2-ol 
• 68690-44-8 neryl p-tolyl sulfone 
• 70238-31-2 1-((Z)-3,7-Dimethyl-6-phenylsulfanyl-octa-2,7-diene-1-sulfonyl)-4-methyl-benzene 
• 70238-35-6 (2E,6Z)-2,6-Dimethyl-8-(toluene-4-sulfonyl)-octa-2,6-dien-1-ol 

Relevant academic research and scientific papers

FACILE FUNCTIONALIZATION OF THE ISOPROPYLIDENE TERMINUS OF ACYCLIC MONOTERPENES BY WAY OF BENZENESULFENYL CHLORIDE ADDITION

Highly site- and regioselective terminal functionalizations of acyclic monoterpenes 1 via benzenesulfenyl chloride addition followed by hydrolysis assisted by silica gel, dehydrochlorination under neutral or weakly basic condition, or dehydrochlorination by strongly basic treatment respectively providing β-hydroxy sulfides 3, terminal methallylic sulfides 4, or vinylsulfides 5 are developed.Conversion of 4 to terminal trans-allylic alcohols 10 via sulfoxides 9 by the Evans procedure is also described.