94853-07-3

Upstream product

• 141-12-8 neryl acetate 
• 16066-31-2 benzenesulfinamide 
• 70473-49-3 Acetic acid (Z)-7-hydroxy-3,7-dimethyl-6-phenylsulfanyl-oct-2-enyl ester 
• 931-59-9 benzenesulfenyl chloride 
• 70238-32-3 Acetic acid (Z)-3,7-dimethyl-6-phenylsulfanyl-octa-2,7-dienyl ester 
• 4972-29-6 benzenesulphinyl chloride 

Relevant academic research and scientific papers

Arenesulfinamides as new reagents for the synthesis of allylic sulfoxides

Reaction of arenesulfinamides with alkenes bearing allylic hydrogens in the presence of Yb(OTf)3/TMSC1 led to the corresponding allylic sulfoxides in good yields.

Regiospecific Ene Reaction of Benzenesulfinyl Chloride with Linear Isoprenoids

The Lewis acid (e.g., ZnCl2) catalyzed ene reaction of benzenesulfinyl chloride with myrcene, geranyl and neryl acetates, as well as ethyl (E,E)-farnesoate proceeds smoothly and chemoselectively by exclusive attack at the terminal trisubstituted C=C bond

FACILE FUNCTIONALIZATION OF THE ISOPROPYLIDENE TERMINUS OF ACYCLIC MONOTERPENES BY WAY OF BENZENESULFENYL CHLORIDE ADDITION

Highly site- and regioselective terminal functionalizations of acyclic monoterpenes 1 via benzenesulfenyl chloride addition followed by hydrolysis assisted by silica gel, dehydrochlorination under neutral or weakly basic condition, or dehydrochlorination by strongly basic treatment respectively providing β-hydroxy sulfides 3, terminal methallylic sulfides 4, or vinylsulfides 5 are developed.Conversion of 4 to terminal trans-allylic alcohols 10 via sulfoxides 9 by the Evans procedure is also described.