948582-29-4Relevant academic research and scientific papers
Biomimetic Total Synthesis of Santalin Y
Strych, Sebastian,Journot, Guillaume,Pemberton, Ryan P.,Wang, Selina C.,Tantillo, Dean J.,Trauner, Dirk
, p. 5079 - 5083 (2015/04/27)
A biomimetic total synthesis of santalin Y, a structurally complex but racemic natural product, is described. The key step is proposed to be a (3+2) cycloaddition of a benzylstyrene to a "vinylogous oxidopyrylium", which is followed by an intramolecular F
Boron trichloride mediated regioselective Claisen rearrangement of resorcinol derivatives: Application to resorcinol carvonyl ethers
Ito, Fumihiro,Fusegi, Keiko,Kumamoto, Takuya,Ishikawa, Tsutomu
, p. 1785 - 1796 (2008/02/12)
Claisen rearrangement (CR) of resorcinol allyl ethers was examined. Although thermal CR gave low regioselectivity, the selectivity was much improved in the presence of a Lewis acid such as boron trichloride. This rearrangement was successfully applied to resorcinol carvonyl ethers for the regioselective introduction of a carvone unit into the resorcinol skeleton for the synthesis of phytoestrogenic miroestrols. Georg Thieme Verlag Stuttgart.
