948859-24-3

Basic information

• Product Name: [bis(1,3,5-triphenylphosphole)allylpalladium(II)] triflate
• CAS NO: 948859-24-3
• Molecular Weight: 921.265
• Mol File: 948859-24-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [bis(1,3,5-triphenylphosphole)allylpalladium(II)] triflate(CAS DataBase Reference)
• NIST Chemistry Reference: [bis(1,3,5-triphenylphosphole)allylpalladium(II)] triflate(948859-24-3)
• EPA Substance Registry System: [bis(1,3,5-triphenylphosphole)allylpalladium(II)] triflate(948859-24-3)

Safety Data

• Hazardous Substances Data: 948859-24-3(Hazardous Substances Data)

Upstream product

• 2923-28-6 silver trifluoromethanesulfonate 
• 1162-70-5 1,2,5-triphenyl-1H-phosphole 

Relevant articles and documents

Testing phosphanes in the palladium-catalysed allylation of secondary and primary amines

The electronic nature of the ligand plays a crucial role in the palladium-catalysed allylation of amines with allylic alcohols. The better the ligand is as a π acceptor, the more active the catalyst. Experiments with a series with mono- and bidentate ligands featuring phosphanes and phospholes applied in the catalytic allylation of aniline clearly demonstrate this. Bolstered by DFT calculations, we have devised a new efficient catalyst for this process which carries the strong π acceptor 1,2,5-triphenylphosphole as a ligand. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.