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94889-67-5

cis-dimethyl(o-tolyl)(triphenylphosphine)gold(III) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 94889-67-5 Structure

  • Basic information

    1. Product Name: cis-dimethyl(o-tolyl)(triphenylphosphine)gold(III)
    2. Synonyms:
    3. CAS NO:94889-67-5
    4. Molecular Formula:
    5. Molecular Weight: 580.46
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 94889-67-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: cis-dimethyl(o-tolyl)(triphenylphosphine)gold(III)(CAS DataBase Reference)
    10. NIST Chemistry Reference: cis-dimethyl(o-tolyl)(triphenylphosphine)gold(III)(94889-67-5)
    11. EPA Substance Registry System: cis-dimethyl(o-tolyl)(triphenylphosphine)gold(III)(94889-67-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 94889-67-5(Hazardous Substances Data)

94889-67-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 94889-67-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,4,8,8 and 9 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 94889-67:
(7*9)+(6*4)+(5*8)+(4*8)+(3*9)+(2*6)+(1*7)=205
205 % 10 = 5
So 94889-67-5 is a valid CAS Registry Number.

94889-67-5Downstream Products

94889-67-5Relevant articles and documents

UNUSUAL STERIC EFFECT OF AN ALKENYL OR ARYL GROUP ON THE DISSOCIATIVE REDUCTIVE ELIMINATION FROM cis-ALKENYL(OR -ARYL)DIMETHYL(TRIPHENYLPHOSPHINE)GOLD(III)

Komiya, Sanshiro,Shibue, Akira,Ozaki, Satoshi

, p. C31 - C34 (1987)

A sterically bulky aryl or alkenyl group directly bonded to gold suppresses the rate of dissociation of the triphenylphosphine ligand from cis-alkenyl(or -aryl)dimethyl(triphenylphosphine)gold(III) leading to selective reductive elimination.

Steric and electronic effects of the tertiary phosphine ligand on the dissociative reductive elimination from cis-aryldimethyl(triarylphosphine)gold(III)

Komiya, Sanshiro,Shibue, Akira

, p. 684 - 687 (2008/10/08)

A series of cis-aryldimethyl(triarylphosphine)gold(III) complexes, cis-Au(C6H4Y)Me2(P(C6H 4X)3) (X = p-OMe, p-Me, H, p-F, o-Me; Y = p-OMe, p-Me, H, p-F, o-OMe, o-Me) and AuPhMe2(P(C6H4-O-Me)nPh 3-n) (n = 0-2), has been prepared by the alkylation of cis-AuMe2IL by the corresponding Grignard reagents. Electron withdrawal from and the steric bulk of the triarylphosphine ligand as well as electron donation by the aryl ligand enhances phosphine dissociation, leading to a facile and selective reductive elimination of aryl Me.

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