94898-40-5

Basic information

• Product Name: 2,3,5-tri-O-benzyl-β-D-arabinofuranosyl fluoride
• Synonyms: 2,3,5-tri-O-benzyl-β-D-arabinofuranosyl fluoride
• CAS NO: 94898-40-5
• Molecular Weight: 422.496
• Mol File: 94898-40-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2,3,5-tri-O-benzyl-β-D-arabinofuranosyl fluoride(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,5-tri-O-benzyl-β-D-arabinofuranosyl fluoride(94898-40-5)
• EPA Substance Registry System: 2,3,5-tri-O-benzyl-β-D-arabinofuranosyl fluoride(94898-40-5)

Safety Data

• Hazardous Substances Data: 94898-40-5(Hazardous Substances Data)

Upstream product

• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 60933-68-8 3,4,6-tri-O-benzyl-β-D-arabinofuranoside 
• 153481-95-9 (2R,3R,4S)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-phenylsulfanyl-tetrahydro-furan 
• 73068-66-3 2,3,5-tri-O-benzyl-β-D-arabinofuranose 
• 96192-07-3 2,3,5-tri-O-benzyl-L-arabinofuranose 

Relevant articles and documents

Synthesis of glyceryl glycosides related to A-type prymnesin toxins

A suite of glycosylated glycerol derivatives representing various fragments of the glycosylated ichthyotoxins called prymnesins were chemically synthesised. Glycerol was used to represent a small fragment of the prymnesin backbone, and was glycosylated at

BrF3-KHF2: An air-stable fluorinating reagent

BrF3-KHF2, an air-stable solid prepared from BrF3 and KHF2, was used in the various fluorination reactions, including desulfurizing fluorination reactions of benzylic sulfides, ketone and aldehyde dithioacetals, (phenylthio)glycosides, and trimethyl trithioorthocarboxylates. As the results, one to three fluorine atoms were selectively introduced to the substrates.

Deoxyfluorination of alcohols using N,N-diethyl-α,α-difluoro- (m-methylbenzyl)amine

Deoxyfluorination of alcohols was carried out using N,N-diethyl-α, α-difluoro-(m-methylbenzyl)amine (DFMBA). Primary alcohols were effectively converted to fluorides under microwave irradiation or conventional heating. Deoxyfluorination of an anomeric hydroxy group in sugars by DFMBA proceeded at below room temperature and glycosyl fluorides could be obtained in good yields. The deoxyfluorination reaction chemoselectively proceeded and various protecting groups on the sugar can survive under the reaction conditions.