949159-75-5

Upstream product

• 910458-85-4 methyl (3S,4S,5R,6S)-6-O-acetyl-4,5-O-cyclohexylidene-3,4,5,6-tetrahydroxy-1-cyclohexene-1-carboxylate 
• 910458-84-3 methyl (4R,5R,6S)-6-O-acetyl-4,5-O-cyclohexylidene-4,5,6-trihydroxy-3-oxo-1-cyclohexene-1-carboxylate 
• 910458-83-2 methyl (1S,2R,3S,4R)-2-O-acetyl-3,4-O-cyclohexylidene-5-oxo-1,2,3,4-tetrahydroxycyclohexanecarboxylate 
• 910458-82-1 methyl (1S,2R,3S,4S,5S)-2-O-acetyl-3,4-O-cyclohexylidene-1,2,3,4,5-pentahydroxycyclohexane-1-carboxylate 
• 910458-79-6 methyl (3R,4R,5S)-5-O-tert-butyldimethylsilyl-3,4-O-cyclohexylidene-3,4,5-trihydroxy-1-cyclohexene-1-carboxylate 
• 910458-80-9 methyl (1S,2R,3S,4R,5S)-5-O-tert-butyldimethylsilyl-3,4-O-cyclohexylidene-1,2,3,4,5-pentahydroxycyclohexane-1-carboxylate 
• 910458-81-0 methyl (1S,2R,3S,4R,5S)-2-O-acetyl-5-O-tert-butyldimethylsilyl-3,4-O-cyclohexylidene-1,2,3,4,5-pentahydroxycyclohexane-1-carboxylate 
• 949159-73-3 methyl (1S,2R,3S,4R,5R)-2-O-acetyl-5-O-tert-butyldimethylsilyl-3,4-O-cyclohexylidene-1,2,3,4,5-pentahydroxycyclohexanecarboxylate 
• 949159-74-4 methyl (1S,2R,3S,4R,5R)-2-O-acetyl-3,4-O-cyclohexylidene-1,2,3,4,5-pentahydroxycyclohexanecarboxylate 
• 168784-03-0 (-)-Methyl 3,4-O-cyclohexylidene-5-didehydroshikimate 
• 120200-03-5 methyl (3aS,4R,7aR)-4-hydroxy-3a,4,5,7a-tetrahydrospiro[benzo[d][1,3]dioxole-2,1'-cyclohexane]-6-carboxylate 
• 193888-31-2 methyl (3R,4S,5S)-3,4-O-cyclohexylidene-3,4,5-trihydroxy-1-cyclohexene-1-carboxylate 
• 811443-44-4 methyl (1S,2R,3S,4R,5R)-5-O-tert-butyldimethylsilyl-3,4-O-cyclohexylidene-1,2,3,4,5-pentahydroxycyclohexanecarboxylate 

Relevant academic research and scientific papers

First total synthesis of antitumor natural product (+)- and (-)-pericosine A: Determination of absolute stereo structure

(Chemical Equation Presented) The first total synthesis of (+)- and (-)-pericosine A has been achieved, enabling the revision and determination of the absolute configuration of this antitumor natural product as methyl (3S,4S,5S,6S)-6-chloro-3,4,5-trihydro

First total synthesis of (-)-pericosine A from (-)-shikimic acid: Structure revision and determination of the absolute configuration of antitumor natural product pericosine A

The first total synthesis of (-)-pericosine A, methyl (3R,4R,5R,6R)-6- chloro-3,4,5-trihydroxy-1-cyclohex-1-enecarboxylate, from (-)-shikimic acid was accomplished, which led to the revision of the relative configuration and the determination of the absol