94934-64-2Relevant academic research and scientific papers
Synthesis and complexation of back-to-back capped bis-dioxocyclams
Gil, Jun Mo,David, Scott,Reiff, Angela L.,Hegedus, Louis S.
, p. 5858 - 5865 (2005)
Pyridine-capped 5,12-dioxocyclams were coupled back-to-back directly, with one or two intervening phenyl groups, an ethynyl group, or a diazo group via Suzuki, Sonogashira, or reductive coupling of the 4-nitropyridine monocyclam. These bis-dioxocyclams linked through extended π-conjugated systems were complexed to copper(II) and cobalt-(III), producing bis-metal complexes which were characterized spectroscopically and electrochemically. These studies gave little evidence for electronic communication between metal centers across the π-conjugated linkers.
An efficient route to biaryl bisbenzocyclobutene monomers based on Suzuki coupling reaction at room temperature
Yang, Jun-Xiao,Ma, Kuo-Yan,Zhu, Fang-Hua,Chen, Wen,Li, Bo,Zhang, Lin,Xie, Ru-Gang
, p. 184 - 186 (2007/10/03)
An efficient and practical preparation of the bisbenzocyclobutene monomers has been developed via the room temperature Suzuki couplings of phenyl-1, 4-diboronic ester with 4-bromobenzocyclobutene or benzocyclobutene-4-boronic acid with aryl dibromides.
