94940-20-2Relevant academic research and scientific papers
Stereoselective Preparation of C-Aryl Glycosides via Visible-Light-Induced Nickel-Catalyzed Reductive Cross-Coupling of Glycosyl Chlorides and Aryl Bromides
Mou, Ze-Dong,Wang, Jia-Xi,Zhang, Xia,Niu, Dawen
, p. 3025 - 3029 (2021)
A nickel-catalyzed cross-coupling reaction of glycosyl chlorides with aryl bromides has been developed. The reaction proceeds smoothly under visible-light irradiation and features the use of bench-stable glycosyl chlorides, allowing the highly stereoselective synthesis of C-aryl glycosides. (Figure presented.).
Remarkable β-selectivity in the synthesis of β-1-C- arylglucosides: Stereoselective reduction of acetyl-protected methyl 1-C-arylglucosides without acetoxy-group participation
Deshpande, Prashant P.,Ellsworth, Bruce A.,Buono, Frederic G.,Pullockaran, Annie,Singh, Janak,Kissick, Thomas P.,Huang, Ming-H.,Lobinger, Hildegard,Denzel, Theodor,Mueller, Richard H.
, p. 9746 - 9749 (2008/03/17)
(Chemical Equation Presented) An efficient and practical process to generate β-C-arylglucoside derivatives was achieved. The process described involves Lewis acid mediated ionic reduction of a peracetylated 1-C-aryl methyl glucoside derived from the addit
