949575-59-1Relevant articles and documents
Synthesis and CD spectroscopy of polyethers with homochiral and heterochiral layers of stereocentres
Brewer, Alice R.E.,Drake, Alex F.,Gibson, Susan E.,Rendell, Jacob T.
, p. 6615 - 6627 (2008/09/21)
Eight polyethers with three to nine stereocentres have been synthesised using chiral base methodology. Examination of the polyethers by CD spectroscopy revealed clear differences between homochiral isomers and isomers with a heterochiral relationship betw
Interplay between core and peripheral chirality in polyethers
Brewer, Alice R.E.,Drake, Alex F.,Gibson, Susan E.,Rendell, Jacob T.
, p. 3487 - 3490 (2008/02/11)
A chiral-base mediated reaction has been used to synthesise the polyethers illustrated and their enantiomers; CD spectroscopy revealed that the homochiral isomers A may be viewed as a C3-symmetric arrangement of fixed paddles while the heteroch