949586-96-3

Basic information

• Product Name: cis-(1R,2S)-2-(phenylseleno)-1-cyclohexanol
• Synonyms: cis-(1R,2S)-2-(phenylseleno)-1-cyclohexanol
• CAS NO: 949586-96-3
• Molecular Weight: 255.218
• Mol File: 949586-96-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-(1R,2S)-2-(phenylseleno)-1-cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: cis-(1R,2S)-2-(phenylseleno)-1-cyclohexanol(949586-96-3)
• EPA Substance Registry System: cis-(1R,2S)-2-(phenylseleno)-1-cyclohexanol(949586-96-3)

Safety Data

• Hazardous Substances Data: 949586-96-3(Hazardous Substances Data)

Upstream product

• 2179-79-5 phenyl selenocyanate 
• 1072-86-2 (1R,2R)-trans-1,2-cyclohexanediol 
• 50984-16-2 rac-2-(phenylseleno)cyclohexanone 

Downstream Products

• 3413-44-3 (R)-2-cyclohexen-1-ol 
• 1022217-08-8 (1S,2S)-1-(phenylsulfanyl)-2-(phenylselanyl)cyclohexane 

Relevant articles and documents

Novel C2-symmetric chiral ligands: enantioselective transformation of cyclic 1,2-diols into 1,2-bis(phenylsulfenyl) and 1,2-bis(phenylselenyl) derivatives

Chiral C2-symmetric S,S- and Se,Se-donating ligands as well as the C1 mixed S,Se-donating ligands were prepared from optically active 1,2-cyclohexanediol and 1,2-cyclopentanediol via the respective SN2 reactions. The bis(chalcogen) ligands obtained effectively catalyze the asymmetric allylic alkylation with enantioselectivities of up to 50% ee.