949886-90-2Relevant academic research and scientific papers
First synthesis of 5-fluoro-(+)-MK7607, its 1-epimer and 6-deoxy derivative
Sardinha, Jo?o,Rauter, Amelia Pilar,Sollogoub, Matthieu
, p. 5548 - 5550 (2008/12/22)
(+)-MK7607 is a patented naturally occurring unsaturated pseudo-carbasugar possessing herbicidal activity. We present herein the first synthesis of the 5-fluorinated analogue (1S, 2S, 3R, 4R)-5-fluoro-6-(hydroxymethyl)cyclohex-5-ene-1,2,3,4-tetrol as well as that of two related compounds, namely its 1-epimer and its 6-deoxy derivative.
gem-Difluoro-carbasugars, the cases of mannopyranose and galactopyranose
Sardinha, Joao,Guieu, Samuel,Deleuze, Aurelie,Fernandez-Alonso, M. Carmen,Rauter, Amelia Pilar,Sinay, Pierre,Marrot, Jerome,Jimenez-Barbero, Jesus,Sollogoub, Matthieu
, p. 1689 - 1703 (2008/02/10)
5a-Difluoro-5a-carbamannopyranose (gem-difluoro-carbamannopyranose) and 5a-difluoro-5a-carbagalactopyranose (gem-difluoro-carbagalactopyranose), close congeners of their respective natural sugars, in which the endocyclic oxygen atom has been replaced by a
