949922-76-3Relevant academic research and scientific papers
Asymmetric Strecker Reaction Arising from the Molecular Orientation of an Achiral Imine at the Single-Crystal Face: Enantioenriched l- and d-Amino Acids
Miyagawa, Shinobu,Yoshimura, Koji,Yamazaki, Yusuke,Takamatsu, Naoya,Kuraishi, Tetsuya,Aiba, Shohei,Tokunaga, Yuji,Kawasaki, Tsuneomi
, p. 1055 - 1058 (2017)
Strecker synthesis has long been considered one of the prebiotic reactions for the synthesis of α-amino acids. However, the correlation between the origin of chirality and highly enantioenriched α-amino acids through this method remains a puzzle. In the r
Replication of α-amino acids: Via Strecker synthesis with amplification and multiplication of chiral intermediate aminonitriles
Aiba, Shohei,Takamatsu, Naoya,Sasai, Taichiro,Tokunaga, Yuji,Kawasaki, Tsuneomi
supporting information, p. 10834 - 10837 (2016/09/09)
Replication of chiral l- and d-α-(p-tolyl)glycine has been achieved in combination with the asymmetric induction, amplification and multiplication of their own chiral intermediates, l- and d-aminonitriles, in the solid-phase via the Strecker reaction between three achiral components, which is a plausible prebiotic mechanism for amino acid synthesis.
TITANIUM COMPOUNDS AND PROCESS FOR CYANATION OF IMINES
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Page/Page column 21; 23, (2012/01/13)
The present invention relates to titanium catalysts for synthesis reactions produced by bringing a reaction mixture comprising a titanium alkoxide and a ligand in contact with water, wherein the ligand is represented by the general formula (e): wherein R
