95012-35-4Relevant academic research and scientific papers
Reaction of Cl with Air; Characterisation of the Products by X-ray Structure Analysis of cis and trans-*MeCN
Organ, Gregory J.,Cooper, Mervyn K.,Henrick, Kim,McPartlin, Mary
, p. 2377 - 2382 (1984)
The chlorohydridorhodium(III) complex of (o-diphenylphosphinophenyl)amine, Cl (1a), formed by oxidative addition of HCl to (6), containing an amino- and amido-donor group, and the trans-dichloro-complex (8).Crystals of (6) are monoclinic, space group P21/n, with a=17.153(3), b=18.667(3), c=9.891(2) Angstroem, β=91.77(3) deg, and Z=4.Blocked full-matrix refinement using 3 501 unique data =3?(I), 3 gave R=0.0487, R'=0.051.Complex (8) crystallises, with a molecule of acetonitril as solvate, in the monoclinic space group I2/c with a=18.394(4), b=14.380(3), c=16.378(3) Angstroem, β=96.67(4) deg, and Z=4.Blocked full-matrix refinement of 2741 reflections with I>=3?(I) (32 symmetry.A mechanism for the reaction is proposed which involves peroxo- and hydrogenperoxo-species.
