950577-49-8Relevant academic research and scientific papers
Iridium-PPh3 Catalysts for Conversion of Amides to Enamines
Une, Yuta,Tahara, Atsushi,Miyamoto, Yasumitsu,Sunada, Yusuke,Nagashima, Hideo
supporting information, p. 852 - 862 (2019/03/04)
Studies on the deactivation mechanism of the reaction of N,N-dialkylamides with TMDS catalyzed by Vaska's complex, IrCl(CO)(PPh3)2 (1a), triggered the discovery of highly active Ir-PPh3 catalysts: Photochemically activated
Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions
Motoyama, Yukihiro,Aoki, Masaharu,Takaoka, Naoki,Aoto, Ryuta,Nagashima, Hideo
supporting information; experimental part, p. 1574 - 1576 (2009/09/06)
The combination of IrCl(CO)(PPh3)2 with 1,1,3,3-tetramethyldisiloxane or poly(methylhydrosiloxane) (PMHS) is found to be an efficient catalyst system for the preparation of aldenamines from carboxamides; in particular, facile removal of silicone and iridium residues from the product can be achieved by the use of PMHS.
Functional group-selective poisoning of molecular catalysts: A ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters
Sasakuma, Hidehiro,Motoyama, Yukihiro,Nagashima, Hideo
, p. 4916 - 4918 (2008/09/17)
The addition of amines eliminates the catalytic activity of a triruthenium cluster in the hydrosilane reduction of ketones and esters without affecting the rate of reduction of amides; selective reduction of the amide group in amido ketones and amido esters is accomplished. The Royal Society of Chemistry.
