950589-69-2Relevant academic research and scientific papers
Multiple C-H activations to construct biologically active molecules in a process completely free of organohalogen and organometallic components
Li, Bi-Jie,Tian, Shi-Liang,Fang, Zhao,Shi, Zhang-Jie
, p. 1115 - 1118 (2008/09/21)
(Chemical Equation Presented) Step by step: Highly selective cross dehydrogenase arylation of acetanilides was developed to construct biaryls under mild condition. With this method, different aryl C-H bonds were activated in sequential reactions to construct functionalized carbazoles (see scheme), which are present as key structural units in various biological molecules and organic optical materials.
Suzuki-Miyaura coupling reaction by PdII-catalyzed aromatic C-H bond activation directed by an N-alkyl acetamino group
Shi, Zhangjie,Li, Bijie,Wan, Xiaobing,Cheng, Jiang,Fang, Zhao,Cao, Bin,Qin, Changming,Wang, Yang
, p. 5554 - 5558 (2008/09/17)
(Chemical Equation Presented) A seamless join: An efficient method to construct a C(sp2)-C(sp2) bond has been developed by using a Suzuki-Miyaura-type coupling of N-alkyl acetanilides with boronic acids. The reaction was catalyzed by
