950603-55-1Relevant academic research and scientific papers
Electrophilic ipso-iodination of silylated arylboronic acids
Durka,Górka,Kurach,Luliński,Serwatowski
experimental part, p. 2635 - 2643 (2010/11/21)
Silylated functionalized arylboronic acids were converted into corresponding iodinated arylboronic acids in good yields via the electrophilic ipso-desilylation effected with iodine chloride in refluxing CHCl3. Disilylated arylboronic acids were susceptible to diiodination. In addition, the structural characterization and reactivity of a novel sterically hindered ortho-silylated diarylborinic ester were reported. The potential of selected iodinated phenylboronic acids as monomers for the Suzuki-Miyaura cross-coupling polymerization was demonstrated.
