95061-78-2Relevant academic research and scientific papers
ELECTRON-TRANSFER PROCESSES IN THE ALKYLATION OF α,β-UNSATURATED SULFONES BY ORGANOMETALLIC REAGENTS
Eisch, John J.,Behrooz, Mohammad,Galle, James E.
, p. 4851 - 4854 (1984)
The alkyldesulfonylation of acetylenic and vinylic sulfones by organolithium and organomagnesium reagents is shown to take place via alkyl radicals arising from electrontransfer processes.
Visible light-driven cross-coupling reactions of alkyl halides with phenylacetylene derivatives for C(sp3)-C(sp) bond formation catalyzed by a B12 complex
Chen, Li,Kametani, Yohei,Imamura, Kenji,Abe, Tsukasa,Shiota, Yoshihito,Yoshizawa, Kazunari,Hisaeda, Yoshio,Shimakoshi, Hisashi
supporting information, p. 13070 - 13073 (2019/11/11)
Visible light-driven cross-coupling reactions of alkyl halides with phenylacetylene and its derivatives catalyzed by the cobalamin derivative (B12) with the [Ir(dtbbpy)(ppy)2]PF6 photocatalyst at room temperature are reported. The robust B12 catalyst and Ir photocatalyst provided high turnover numbers of over 33?000 for the reactions.
