95062-51-4Relevant academic research and scientific papers
4,6-Dimethyl-o-quinone methide and 4,6-dimethylbenzoxete
Guang, Greg,Qiao, Hua,Lenghaus, Keith,Solomon, David H.,Reisinger, Ales,Bytheway, Ian,Wentrup, Curt
, p. 9806 - 9811 (1998)
4,6-Dimethyl-o-quinone methide (4) was produced by FVP of alcohol 3 or of the trimer 6 and matrix isolated in Ar at 7.6 K. Photolysis of 4 with long wavelength light (>345 nm) at this temperature afforded 4,6-dimethylbenzoxete (5), which was observable up to room temperature in the solid state in the absence of water. 5 can be converted back to 4 by UV irradiation at 254/190 nm. Quantum chemical calculations on the thermal interconversion of 4 and 5 indicate activation barriers of the order of 40 kcal/mol for 4 → 5, and 30 kcal/mol for 5 → 4. The dimer, trimer, and tetramer (8, 6, and 7) of 4 are characterized.
