95069-16-2Relevant academic research and scientific papers
PHOSPHA-S-TRIAZINES. VIII. CHLORO-SUBSTITUTED DIPHOSPHA-S-TRIAZINES
Paciorek, K. J. L.,Harris, D. H.,Smythe, M. E.,Nakahara, J. H.,Kratzer, R. H.
, p. 387 - 398 (1985)
1,3-Bis(phenylchlorophospha)-5-perfluoroalkyl-2,4,6-triazine and the corresponding perfluoroalkylether analogue were synthesized by interaction of equimolar amounts of the respective amidines and imido-diphenyl-diphosphinic acid pentachloride.With additional quantities of amidine, 1,3-bis(phenylperfluoro-n-octanoylamidinophospha)-5-perfluoro-n-heptyl-2,4,6-triazine was obtained.The replacement of the chloro- by azido-groups in 1,3-bis(phenylchlorophospha)-5-perfluoro-n-heptyl-2,4,6-triazine proceeded readily.The mass spectral breakdown patterns of the chloro- and the amidinosubstituted compounds were directly comparable to those of the bis(diphenylphospha)-s-triazines.
