950692-85-0Relevant academic research and scientific papers
A novel, facile route to β-fluoroamines by hydrofluorination using superacid HF-SbF5
Thibaudeau, Sebastien,Martin-Mingot, Agnes,Jouannetaud, Marie-Paule,Karam, Omar,Zunino, Fabien
, p. 3198 - 3200 (2007)
A range of unsaturated amines and sulfonamides were converted to β-fluoro nitrogen analogues after hydrofluorination in superacid HF-SbF5, based on the formation of highly reactive electrophilic intermediates. The Royal Society of Chemistry.
Substitution effect on the hydrofluorination reaction of unsaturated amines in superacid HF/SbF5
Liu, Fei,Martin-Mingot, Agnes,Jouannetaud, Marie-Paule,Karam, Omar,Thibaudeau, Sebastien
experimental part, p. 4789 - 4797 (2009/12/08)
This paper describes the scope and limitations of the hydrofluorination reaction in superacid HF/SbF5. On the basis of experimental studies of polyfunctional substrates' behaviour, the dramatic effect of substitution on the superelectrophilic c
