95071-03-7Relevant academic research and scientific papers
1,6-Conjugate addition of boronic acids to 2-allylidenemalonates
De La Herrán, Gabriela,Csák?, Aurelio G.
body text, p. 585 - 588 (2009/07/09)
The addition of boronic acids to 2-allylidenemalonates under RhI or Pd2+ catalysis shows an enhanced selectivity for the 1,6-addition reaction in comparison with diunsaturated monoesters. In the case of the RhI-catalyzed addition, the position of the new C=C double bond in the final product can be tuned with the choice of the base to give vinylmalonates of alkylidenemalonates. Georg Thieme Verlag Stuttgart.
