950736-00-2Relevant academic research and scientific papers
Design and synthesis of Sn-porphyrin based molecular gates
Guenet, Aurelie,Ernest Graf,Nathalie Kyritsakas,Hosseini, Mir Wais
, p. 1872 - 1883 (2010)
The design, synthesis, and structural characterization, both in solution by 1H NMR and in the solid state by X-ray diffraction on single crystals, of a series of molecular gates based on Sn-porphyrin derivatives are presented. The molecular systemis based on a porphyrin core bearing at the meso positions either phenyl or pyridyl groups as a stator, octahedral Sn(IV) cation located at the center of the porphyrin as a hinge, and different handles connected to the porphyrin through Sn-O axial bonds. The stability of the complexes in the presence of different acids is also reported.
A molecular gate based on a porphyrin and a silver lock
Guenet, Aurelie,Graf, Ernest,Kyritsakas, Nathalie,Allouche, Lionel,Hosseini, Mir Wais
, p. 2935 - 2937 (2008/02/10)
A Sn(IV) metallaporphyrin bearing a 4-pyridyl group on one meso position and a handle equipped also with a pyridyl unit functions in solution as a molecular gate in the presence of silver cation: the complexation-decomplexation of Ag(i) corresponds to the
